A 5.00 10-2 M solution of unknown monoprotic weak base has a pH of 9.300. What is the value of Kb for the base?|||a monoprotic base dissociate as follows:
AOH ←→ A⁺ + OH⁻
with
Kb = [A⁺]·[OH⁻] / [AOH]
negliging the self dissociation of water same amounts of OH⁻ and A⁺ are formed in equilibrium, hence:
[A⁺] = [OH⁻]
The concentration of nondissiociated base drops to:
[AOH] = [AOH]₀ - [OH⁻]
The dissociation equilibrium of water is given by:
[H⁺]·[OH⁻] = Kw = 10^-14
hence
log[H⁺] + log[OH⁻] = -14
%26lt;=%26gt;
log[OH⁻] = -14 - log[H⁺]
%26lt;=%26gt;
[OH⁻] = 10^(-14+pH)
= 2.0×10-5 M
=%26gt;
[AOH] = [AOH]₀ - [OH⁻]
= 5×10-2 M - 2.0×10-5 M
= 4.998×10-2 M
=%26gt;
Kb = [A⁺]·[OH⁻] / [AOH]
= 2.0×10-5 · 2.0×10-5 / 4.998×10-2
= 8.0×10-9 M
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